000 02818nab a2200397Ia 4500
001 Art-401
008 170220s2013 CNT 000 0 und d
020 _a0039-3630
099 _aR: 3023
245 1 0 _aThe application of subcritical fluids for the stabilization of marine archaeological iron
300 _a12 p.
310 1 0 _aTrimestral
520 3 _aThe long-term stabilization of marine archaeological iron, whether cast or wrought, continues to challenge conservators responsible for treatment of this material. Results and observations obtained from past treatments highlight the daunting, prolonged, and laborious efforts required to desalinate large and complex ferrous artifacts recovered from the ocean. In general, the higher an artifact's chloride level, the less stable it is. Consequently, any stabilization treatment must involve the removal of as much Cl−1 as possible without affecting the integrity of the corroded artifact. This problem is particularly acute with corroding cast iron objects that have formed thick, fragile, and highly unstable corrosion layers. Over the course of the twentieth century, conservators have used a variety of techniques in an attempt to mitigate the negative effects of chloride ions on iron artifacts and prevent disintegration. In spite of early promise, each of these stabilization techniques has significant disadvantages, particularly with regard to treatment efficiency, duration of treatment, and/or unacceptable risks to the artifact during treatment. For these reasons, conservators and conservation scientists at the Warren Lasch Conservation Center in Charleston, South Carolina, decided to look at the possibility of using subcritical fluids to stabilize archaeological iron. This paper compares the efficiency and effectiveness of traditional stabilization techniques (i.e. alkaline soaking and cathodic polarization) to subcritical fluids on wrought iron rivets and metal shavings from the H.L. Hunley submarine as well as Civil War era cast iron artillery shells recovered from a marine environment.
650 _aChloride
650 _aClorur
650 _aCloruro
650 _aConservació de Metalls
650 _aConservación de Metales
650 _aCorrosió del ferro
650 _aCorrosión de hierro
650 _aDesalination
650 _aDesalinización
650 _aDessalinització
650 _aEstabilització de Ferro
650 _aEstabilización de Hierro
650 _aIron corrosion
650 _aIron stabilization
650 _aMetals conservation
650 _aParticular
650 _aSubcritical
700 1 _aDE VIVÉS, P.
700 1 _aDREWS, M.J.
700 1 _aGONZÁLES-PEREYRA, N.G.
700 1 _aMARDIKIAN, P.
773 _tStudies in conservation 3
_x0039-3630
_g58 4, 314-325
999 _c8092
_d8092